程建華

男， 中國(guó)科學(xué)院長(zhǎng)春應(yīng)用化學(xué)研究所， 教授/研究員/教授級(jí)高工或同等級(jí)別

學(xué)習(xí)/工作經(jīng)歷

1993-1997 吉林工業(yè)大學(xué)，理學(xué)院，應(yīng)用化學(xué)，本科
1997-2003 中國(guó)科學(xué)院長(zhǎng)春應(yīng)用化學(xué)研究所，高分子化學(xué)，博士
2003-2009 加拿大University of Alberta，博士后
2009-2013 日本理化學(xué)研究所(RIKEN)，特別研究員
2013-至今 中國(guó)科學(xué)院長(zhǎng)春應(yīng)用化學(xué)研究所，研究員，博士生導(dǎo)師

研究領(lǐng)域和興趣

金屬有機(jī)化學(xué)與烯烴聚合

主要業(yè)績(jī)

多年來(lái)一直從事有關(guān)金屬有機(jī)化學(xué)方面的研究，主要關(guān)注于堿土金屬、錒系金屬和稀土金屬配合物的結(jié)構(gòu)、反應(yīng)性的研究，以及新型過(guò)渡金屬烯烴聚合催化劑的設(shè)計(jì)與合成。在國(guó)內(nèi)外知名學(xué)術(shù)期刊，如:J. Am. Chem. Soc., Angew. Chem. Int. Ed., ACS Catal., Chem. Sci., Chem. Commun., Macromolecules 等 SCI 雜志上發(fā)表論文 50 多篇。合成了首例二價(jià)稀土金屬銩胺基、烷基以及硼氫化合物；報(bào)道了一系列非茂基稀土金屬氫化物的結(jié)構(gòu)以及與有機(jī)小分子的反應(yīng)性，分離和表征了一氧化碳還原、偶聯(lián)轉(zhuǎn)化為丙烯過(guò)程中的重要中間體；設(shè)計(jì)了雙核茂基稀土金屬鈧催化劑，可以作為雙官能引發(fā)劑合成ABA三嵌段共聚物，獲得了在中部嵌段中具有完美的間同聚苯乙烯和在兩末端嵌段中具有可調(diào)節(jié)聚已內(nèi)酯含量的PCL-b-sPS-b-PCL三嵌段共聚物。

代表成果

1. Runhai Chen?, Guorui Qin?, Shihui Li, Alision. J. Edwards*, Ross. O. Piltz, Iker Del Rosal, Laurent Maron*, Dongmei Cui, Jianhua Cheng*, “Molecular Thorium Trihydrido Clusters Stabilized by Cyclopentadienyl Ligands”, Angew. Chem. Int. Ed., 2020, 59, 11250-11255, Doi: 10.1002/anie.202002303.
2. Xianghui Shi, Guirui Qin, Yang Wang, Langxiao Zhao, Zhizhou Liu, Jianhua Cheng*, “Super-Bulky Penta-arylcyclopentadienyl Ligands: Isolation of the Full Range of Half-Sandwich Heavy Alkaline-Earth Metal Hydrides”, Angew. Chem. Int. Ed., 2019, 58, 4356-4360, Doi: 10.1002/anie.201814733.
3. Xianghui Shi, Cuiping Hou, Chulu Zhou, Yanyao Song, Jianhua Cheng*, “A Molecular Barium Hydrido Complex Stabilized by a Super-Bulky Hydrotris(pyrazolyl)borate Ligand”, Angew. Chem. Int. Ed., 2017, 56, 16650-16653, Doi: 10.1002/anie.201709344.
4. Lanxiao Zhao, Peng Deng, Xun Gong, Xiaohui Kang*, Jianhua Cheng*, “Regioselective C-H Alkylation of Aromatic Ethers with Alkenes by Half-Sandwich Calcium Catalyst”, ACS Catal., 2022, 12, 7877-7885, Doi:10.1021/acsctal.2c01572.
5. Lanxiao Zhao, Xianghui Shi, Jianhua Cheng,* “Calcium-Catalyzed Dehydrogenative Silylation of Aromatic Ethers with Hydrosilane", ACS Catal., 2021, 11, 2041-2046, Doi: 10.1021/acscatal.0c05440.
6. Xianghui Shi, Peng Deng, Thayalan Rajeshkumar, Lauren Maron*, Jianhua Cheng*, “Multi-electron redox reactivity of a samarium(II) hydrido complex”, Chem. Sci., 2024, 58, Doi: 10.1039/d4sc03104k.
7. Lanxiao Zhao, Peng Deng, Xun Gong, Jianhua Cheng*, “Tandem Synthesis of Linear Hydridopolycarbosilanes and Postfunctionalization by a Calcium Catalyst”, Macromolecules 2023 56, 9550-9558, Doi: 10.1021/acs.macromol.3c02049.
8. Peng Deng, Lipeng Sang, Xun Gong, Xiang Guo, Jianhua Cheng*, “Syndiotactic (Co)polymerization of 4‐Vinylbenzocyclobutene Catalyzed by Rare-Earth Metal Complex”, Macromolecules 2024 57, 6166-6176, Doi: 10.1021/acs.macromol.4c00958.
9. Yang Wang, Chulu Zhou, Jianhua Cheng*, “Binuclear Scandium Initiators for the Syndiospecific Triblock Copolymerization of Styrene with ?-Caprolactone”, Macromolecules 2020, 53, 3332-3338, Doi:10.1021/acs.macromol.9b02602.
10. Xianghui Shi, Cuiping Hou, Langxiao Zhao, Peng Deng, Jianhua Cheng*, “Mononuclear Calcium Complex as Effective Catalyst for Alkenes Hydrogenation”, Chem. Commun., 2020, 56, 5162-5165, Doi: 10.1039/d0cc01745k.

*以上信息由高級(jí)會(huì)員個(gè)人更新和維護(hù)。